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71.
以1,3-二苯基异苯并呋喃(1,3-Diphenylisobenzofuran, DPBF)为荧光探针, 研究了姜黄素(Curcumin, CUR)在铜离子催化下产生的单线态氧(1O2), 其反应机理为姜黄素与溶液中的氧分子快速作用产生O2·-和H2O2等活性氧物种, 同时Cu2+与姜黄素形成复合物, 再与H2O2形成过氧化物过渡态, 过氧化物进一步与H2O2发生类Haber-Weiss反应生成1O2, 且只有Cu2+和Cu+离子可催化姜黄素并产生1O2. 1O2在1.37×10-8~3.66×10-7 mol/L浓度范围内与荧光强度下降值ΔIF有良好的线性关系, 检出限为4.12×10-9 mol/L. 相似文献
72.
We discuss the quenching phenomena for a system of heat equations coupled with nonlinear boundary flux. We determine a critical value for the exponents in the boundary flux, such that only in the super critical case the simultaneous quenching can happen for any solution. 相似文献
73.
LI Junfeng LIU Weian 《偏微分方程(英文版)》2009,(3):266-281
This paper is concerned with the asymptotic behavior of solution to the following model involving two species all with chemotaxis:{αp/αt=Dp△(p△lnp/w),αp/αt=Dq△(q△lnq/w),αw/αt=βp-δw,p△ln(p/w).^-n=q△ln(q/w).^-n=0.We prove that the solution exists globally asβ ≥ 0. Asβ 〈 0, whether the solution exists globally or not depends on the initial data. By function transformation and compari- son, the asymptotical behavior of the solution is studied. 相似文献
74.
The interaction of colloidal TiO2 nanoparticles with calf thymus-DNA was studied by using absorption, FT-IR, steady state and time resolved fluorescence spectroscopic techniques. The apparent association constant has been deduced (Kapp = 2.85 × 103 M−1) from the absorption spectral changes of the DNA-colloidal TiO2 nanoparticles using the Benesi–Hildebrand equation. Addition of colloidal TiO2 nanoparticles quenched the fluorescence of EtBr–DNA. The number of binding sites (n = 0.97) and the apparent binding constant (K = 6.68 × 103 M−1) were calculated from relevant fluorescence quenching data. The quenching, through a static mechanism, was confirmed by time resolved fluorescence spectroscopy. 相似文献
75.
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77.
一种蓝光单体的合成及其荧光性能研究 总被引:1,自引:0,他引:1
吡唑啉衍生物在生物医药[1,2]应用的领域非常广泛.吡唑啉还是一种优质的发光材料[3],其发射波长位于450nm左右,具有很高的荧光量子效率,且发光波长窄,色纯度好,是一种纯正的蓝光.当吡唑啉环3位引入给电子基时,化合物则具有很高的荧光量子产率,可制得具有高热稳定性的空穴传输蓝光发光材料[4-6]和荧光探针[7].它还可以将吸收的不可见的紫外光转变为蓝色的可见光反射出来,从而增加了光线的反射率,使被其处理过的物体白度和光泽提高,所以吡唑啉又被做为荧光增白剂和荧光染料[8,9]进行广泛地应用. 相似文献
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79.
Hui Cao Donghui Wu Hongxian Wang Ming Xu 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,73(5):972-975
In this paper, two flavonoid aglycones (baicalein, quercetin) and their glycosides (baicalin, quercitrin) were studied for their ability to bind protein by quenching the protein intrinsic fluorescence. From the spectra obtained, the bimolecular quenching constants, the apparent static binding constants, and binding sites values were calculated. The glycosylation of flavonoids decreases the binding affinity with protein. For quercetin and quercitrin, the binding constants for BSA were 3.65 × 107 and 6.47 × 103 L mol−1, respectively. For baicalein and baicalin, the binding constants were 4.54 × 108 and 1.63 × 106 L mol−1, respectively. 相似文献
80.
Siavash Riahi Mohammad Reza Ganjali Maryam Hariri Shaghayegh Abdolahzadeh Parviz Norouzi 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,74(1):253-258
In this paper, a sensitive, easy, efficient, and suitable method for the calculation of Kf values of complexation between one derivative of Dansyl chloride [5-(dimethylamino) naphthalene-1-sulfonyl 4-phenylsemicarbazide] (DMNP) and Lanthanide(III) (Ln) ions is proposed, using both spectrofluorometric and spectrophotometric methods. Determination of Kf showed that DMNP was mostly selective towards the erbium (III) ion. The validity of the method was also confirmed calculating the Stern–Volmer fluorescence quenching constants (Ksv) that resulted in the same consequence, obtained by calculating the Kf of complexation values. In addition, the UV–vis spectroscopy was applied for the determination of Kf only for the Ln ions that had interactions with DMNP. Finally, the DFT studies were done on Er3+ and the DMNP complex for distinguishing the active sites and estimating the pair wise interaction energy. It can be concluded that this derivative of Dansyl chloride with inherent high fluorescence intensity is a suitable reagent for the selective determination of the Er3+ ion which can be used in constructing selective Er3+ sensors. 相似文献